La Femme Nikita S1E1

Nikita is a drug-addicted juvenile delinquent who was accused of killing a police officer in cold blood during an attempted robbery of a pharmacy. She is later arrested and sentenced to death by lethal injection, upon which she was secretly drugged by the government, faking her death. Nikita is then "recruited" by a secret government organization and transformed into a highly skilled assassin who cannot be traced.